Pentane and tetrahydrofuran solvates of trans‐dichlorobis[1,2‐ethanediylbis(diphenylphosphine)‐P,P′]molybdenum(II) |
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Authors: | Alexander Filippou Peter Portius Athanassios Philippopoulos Gabriele Kociok‐Khn Burkhard Ziemer |
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Institution: | Alexander Filippou,Peter Portius,Athanassios Philippopoulos,Gabriele Kociok‐Köhn,Burkhard Ziemer |
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Abstract: | trans‐MoCl2(dppe)2] dppe is 1,2‐ethanediylbis(diphenylphosphine), C26H24P2] was obtained as a side product from the reaction of trans‐Mo(dppe)2(N2)2] with Cp*GeCl to give the germylyne complex trans‐Cl(dppe)2Motriple‐bond]Ge(η1‐Cp*)]. The crystal structures of the hemipentane (0.5C5H12) and ditetrahydrofuran (2C4H8O) solvates of trans‐MoCl2(dppe)2], (IIIa) and (IIIb), respectively, have been determined. |
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