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Ethyl 2‐benzyl‐2‐nitro‐3‐phenyl­propanoate
Authors:Tod J Miller  Yanwen Fu  Frank R Fronczek  Robert P Hammer
Abstract:The title compound, C18H19NO4, is the key synthetic intermediate in the preparation of α,α‐di­benzyl‐α‐amino acid (di­benzyl­glycine, Dbg), the disubstituted homologue of phenyl­alanine, following the di­alkyl­ation of ethyl nitro­acetate. The mol­ecule does not have its potential mirror symmetry in the crystal, with the two benzyl groups forming N—C—C—C torsion angles of 60.31 (13) and 79.89 (13)°.
Keywords:
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