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Aqua­nitro(α,β,γ,δ‐tetra­phenyl­porphy­rinato)­cobalt(III) N,N‐di­methyl­form­amide disolvate
Authors:Shigeru Ohba  Makoto Eishima  Hiroshi Seki
Abstract:In the title compound, Co(tpp)(NO2)(H2O)]·2dmf or Co(C44H28N4)(NO2)(H2O)]·2C3H7NO, a distorted octahedral CoIII complex shows an orientational disorder such that the positions of the nitro and aqua ligands are exchanged. As a result, the averaged structure has an inversion centre at the Co atom. The di­methyl­form­amide mol­ecule also has a positional disorder.
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