Aquanitro(α,β,γ,δ‐tetraphenylporphyrinato)cobalt(III) N,N‐dimethylformamide disolvate |
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Authors: | Shigeru Ohba Makoto Eishima Hiroshi Seki |
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Abstract: | In the title compound, Co(tpp)(NO2)(H2O)]·2dmf or Co(C44H28N4)(NO2)(H2O)]·2C3H7NO, a distorted octahedral CoIII complex shows an orientational disorder such that the positions of the nitro and aqua ligands are exchanged. As a result, the averaged structure has an inversion centre at the Co atom. The dimethylformamide molecule also has a positional disorder. |
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