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Diaqua{6,6′‐dimethoxy‐2,2′‐[propane‐1,3‐diylbis(nitrilomethylidyne‐N)]diphenolato‐O,O′}nickel(II)
Authors:Ligia Gomes  Carla Sousa  Cristina Freire  Balt­azar de Castro
Abstract:In the title compound, Ni(C19H20N2O4)(H2O)2], the Ni atom has a distorted octahedral coordination geometry in which the tetradentate Schiff base ligand acts as a cis‐N2O2 donor defining an equatorial plane, and water mol­ecules occupy the axial positions. The two parts of the mol­ecule are related by a mirror plane that passes through the Ni atom and is perpendicular to the equatorial plane. The angular distortions from normal octahedral geometry are in the range 1–6°, and the equatorial plane, defined by the donor atoms of the Schiff base, is almost square planar. The six‐membered ring comprising the Ni, the imine N and the propyl­ene C atoms adopts a half‐chair conformation. The Ni—O 2.017 (2) Å] and Ni—N 2.071 (2) Å] distances are within the ranges expected for high‐spin octahedral nickel complexes.
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