The allyl complex di‐μ‐chloro‐bis{[(1,2,3‐η)‐4‐oxo‐5,5‐dimethyl‐1‐(ethoxycarbonyl)hexenyl]palladium(II)} |
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Authors: | Anthony L. Spek Johannes Canisius Hans Preut Norbert Krause |
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Abstract: | The title compound, di‐μ‐chloro‐bis{[(2,3,4‐η)‐ethyl 6,6‐dimethyl‐5‐oxohept‐2‐enoato]palladium(II)}, [Pd2Cl2(C11H17O3)2], is a binuclear chloro‐bridged palladium allyl complex that was obtained serendipitously From the reaction of 6,6‐dimethyl‐2‐hepten‐4‐ynoate with Na2PdCl4 in water‐containing alcohol. The allyl group is substituted with an ester and a tert‐butylcarboxy group. The dimeric molecules link via C—H?O contacts into a two‐dimensional network parallel to the bc plane. |
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