A ruthenium(II) complex with p‐cymene and (S)‐2‐(anilinomethyl)pyrrolidine |
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Authors: | Mustapha Aitali,Larbi El Firdoussi,Abdellah Karim,Alejandro F. Barrero,Miguel Quir s |
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Affiliation: | Mustapha Aitali,Larbi El Firdoussi,Abdellah Karim,Alejandro F. Barrero,Miguel Quirós |
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Abstract: | The title compound, [(S)‐2‐(anilinomethyl)pyrrolidine‐N,N′]‐chloro(η6‐para‐cymene)ruthenium(II) chloride, [RuCl‐(C10H14)(C11H16N2)]Cl, has been synthesized by the reaction of [RuCl2(p‐cymene)]2 (p‐cymene is para‐isopropyltoluene) with (S)‐2‐(anilinomethyl)pyrrolidine in triethylamine/2‐propanol. The Ru atom is in a pseudo‐tetrahedral environment coordinated by a chloride ligand, the aromatic hydrocarbon is linked in a η6 manner and the amine is linked via its two N atoms. The chloride anion is involved in hydrogen bonding with the diamine moieties through N—H?Cl interactions, with N?Cl distances of 3.273 (4) and 3.352 (4) Å. |
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