| 非合成气法烯烃、炔烃氢甲酰化研究进展 |
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| 引用本文： | 潘茵茵,宋广杰,薛宽荣,许胜.非合成气法烯烃、炔烃氢甲酰化研究进展[J].分子催化,2021,35(2):166-177. |
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| 作者姓名： | 潘茵茵 宋广杰 薛宽荣 许胜 |
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| 作者单位： | 华东理工大学化学与分子工程学院 |
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| 基金项目： | 国家科技攻关计划;国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 摘 要： | 烯烃、炔烃的氢甲酰化反应是制备醛及其衍生物的重要反应,传统的过渡金属催化合成气(CO/H2)合成法,因为价格低廉,工艺成熟,在工业上得到了广泛应用.然而合成气的高毒性、高危性限制了它的实验室研究,因此使用非合成气的氢甲酰化反应吸引了化学家的研究兴趣.采用非一氧化碳(CO)为羰基源的新型氢甲酰化研究发展迅速,我们对该领域...
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| 关 键 词： | 烯烃 炔烃 非合成气 氢甲酰化 |
| 收稿时间： | 2020/10/10 0:00:00 |
| 修稿时间： | 2020/12/16 0:00:00 |
The Development of Hydroformylation of Alkenes and Alkynes with Syngas Substitutes |
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| PAN Yin-yin,SONG Guang-jie,XUE Kuan-rong and XU Sheng.The Development of Hydroformylation of Alkenes and Alkynes with Syngas Substitutes[J].Journal of Molecular Catalysis (China),2021,35(2):166-177. |
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| Authors: | PAN Yin-yin SONG Guang-jie XUE Kuan-rong and XU Sheng |
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| Institution: | East China University of Science Technology |
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| Abstract: | Hydroformylation of alkenes and alkynes is an important reaction for the preparation of aldehydes and their derivatives. Traditional synthesis methods using syngas (CO/H2) as substrates have achieved great success in industry. However, syngas is toxicity and risk, limiting its laboratory research and application. In recent years, hydroformylation with syngas substitutes has attracted much attention in the organic synthesis. New hydroformylation with syngas substitutes has been developed rapidly. In this paper, the development of hydroformylation in recent years was reviewed. The alternatives to syngas such as HCHO, CO2, HCOOH, glyoxylic acid and alcohol are introduced one by one. Finally, the future development of hydroformylation is prospected. |
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| Keywords: | alkenes alkynes non syngas hydroformylation reaction |
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