Abstract: | The title complex, [PtCl2(C6H7NO)(C2H6OS)], exhibits square‐planar geometry. The plane of the pyridine ring makes a dihedral angle of 67.2 (3)° with the square plane of the metal center. The S—O bond is nearly aligned with the adjacent Pt—N bond, leaving the methyl groups of the dimethyl sulfoxide ligand to stagger the Pt—Cl bond. |