Abstract: | The maleonitrile moiety of the title compound, (2Z)‐2,3‐bis[(4‐nitrobenzyl)sulfanyl]but‐2‐enedinitrile, C18H12N4O4S2, is almost planar. The two benzene rings are nearly parallel to each other and perpendicular to the maleonitrile plane. Intermolecular S?S and π–π interactions are observed in the crystal structure. |