Bis(μ‐pyridine‐2,6‐carboxylato‐O,N,O′:O)bis[triaquamanganese(II)]–pyridine‐2,6‐dicarboxylic acid (1/2) |
| |
Authors: | Nobuo Okabe Naomi Oya |
| |
Abstract: | In the structure of the title compound, Mn2(C7H3NO4)2(H2O)6]·2C7H5NO4, a centrosymmetric dinuclear complex, hexaaaquabis(pyridine‐2,6‐dicarboxylato)dimanganese(II) and free pyridine‐2,6‐dicarboxylic acid are present in a 1:2 ratio. In the complex, each Mn2+ ion is coordinated by three O atoms and one N atom from the pyridine‐2,6‐dicarboxylate ligands and by three water O atoms, resulting in a distorted pentagonal bipyramidal coordination. Within the centrosymmetric dinuclear complex, two Mn2+ ions are bridged by two carboxylate O atoms. The crystal structure is stabilized by hydrogen bonds involving all the H atoms of the water ligands. |
| |
Keywords: | |
|
|