Two-tone frequency modulation spectroscopy for ambient-air trace gas detection using a portable difference-frequency source around 3 μm |
| |
Authors: | P Maddaloni P Malara G Gagliardi P De Natale |
| |
Institution: | (1) Istituto Nazionale di Ottica Applicata and European Laboratory for Nonlinear Spectroscopy (LENS), Comprensorio ‘A. Olivetti’, Consiglio Nazionale delle Ricerche, Via Campi Flegrei 34, 80078 Pozzuoli, Italy |
| |
Abstract: | We report a portable, widely tunable, mW-power mid-infrared spectrometer based on difference-frequency generation in a periodically poled lithium-niobate crystal, realized in a compact and robust design. The analytical performance for real-time monitoring of natural-abundance trace gases in ambient air is evaluated, pointing out the possibility of field applications. In a direct-absorption scheme, a minimum detectable concentration of 3 ppb Hz-1/2 is demonstrated around 3.3 μm for methane at atmospheric pressure. The sensitivity is further improved by using a two-tone frequency modulation spectroscopy technique that provides an enhancement of a factor of 100 in the signal-to-noise ratio, thus yielding a minimum absorption coefficient of 5.3×10-9 cm-1 Hz-1/2. PACS 42.72.Ai; 42.81.Wg; 42.68.Ca |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|