| 光诱导的二芳基烯丙醇氰甲基化合成δ-酮腈的反应研究 |
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| 引用本文： | 杜琳琳,李铁生.光诱导的二芳基烯丙醇氰甲基化合成δ-酮腈的反应研究[J].有机化学,2020(1):140-148. |
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| 作者姓名： | 杜琳琳 李铁生 |
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| 作者单位： | 郑州大学化学与分子工程学院 |
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| 摘 要： | 以二芳基烯丙醇与溴乙腈为原料,开发了一种可见光诱导的合成δ-酮腈的方法.控制实验的结果表明,该反应可能是通过自由基机理进行的,溴乙腈作为氰甲基自由基源参与到反应中.
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| 关 键 词： | 可见光诱导 二芳基烯丙醇 自由基 |
Visible-Light Induced Cyanomethylation of Diaryl Allyl Alcohols to Synthesize δ-Ketonitriles |
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| Du Linlin,Li Tiesheng.Visible-Light Induced Cyanomethylation of Diaryl Allyl Alcohols to Synthesize δ-Ketonitriles[J].Chinese Journal of Organic Chemistry,2020(1):140-148. |
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| Authors: | Du Linlin Li Tiesheng |
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| Institution: | (Henan Key Laboratory of Chemical Biology and Organic Chemistry,Key Laboratory of Applied Chemistry of Henan Universities,College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450052) |
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| Abstract: | A photocatalyzed method for the synthesis of δ-ketonitriles from the reaction of diaryl allyl alcohols with bromoacetonitrile is developed. The result of control experiments indicates that the reaction might proceed via a free radical mechanism and bromoacetonitrile was the source of cyanomethyl radical. |
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| Keywords: | photocatalyzed diaryl allyl alcohol radical |
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