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An alternative view of condensed-phase photoionization
Authors:Ma Xiao-Guang  Yang Chuan-Lu  Gong Yu-Bing and Wang Mei-Shan
Institution:Department of Physics, Ludong University, Yantai 264025, China
Abstract:This paper proposes an accurate valuable interpretation scheme to study the evolvement of the photoionization processes from the isolated to the condensed atoms by a unique ab initio method. The variations of the photoionization cross sections of the atomic sodium with the photoelectron energy and the boundary radius of the atomic configuration space are studied in this new scheme by the R-matrix method. The discrepancy in the photoionization spectra of the isolated and the condensed sodium has been explained quantitatively and understood successfully by this alternative view in detail for the first time.
Keywords:condensed-phase photoionization  sodium  configuration space
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