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Formation of conductive layers inside diamond by hydrogen ion implantation and subsequent thermal treatment at low or high pressures
Authors:V P Popov  L N Safronov  O V Naumova  V A Volodin  I N Kupriyanov  Yu N Pal’yanov
Institution:1. Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Abstract:(111) synthetic HPTP diamond plates are irradiated by H 2 + 50 keV ions in the range of the fluences of 1?13 × 1016 sm?2 and annealed in vacuum at 1 mPa (VPHT, 500?C1600°C) or at high HPHT parameters (4.0?C7.5 GPa, 1200?C1550°C). It is shown by measuring the layer conductivity and Raman light scattering that after VPHT annealing, a buried layer of glassy carbon 10?C100 nm thick with low resistance (??1 kOhm/??) is formed, followed by HPHT with high resistance (??1 MOhm/??) and hopping transport along defects.
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