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Photometric determination of palladium with the inclusion complex 1,2-Diaminoanthraquinone-β-cyclodextrin as ligand
Authors:Francisco Garcia Sanchez  Miguel Hernandez Lopez  Eduardo de Gracia Villodres
Affiliation:(1) Department of Analytical Chemistry, Faculty of Sciences, The University, E-29071 Malaga, Spain
Abstract:1,2-Diaminoanthraquinone forms a 1ratio1 inclusion complex withbeta-cyclodextrin in aqueous media and at different pH. This can be employed to solubilize the anthraquinone in water for use as a ligand for metal ions. This ligand can be used to determine palladium at trace levels spectrophotometrically. The limit of detection is 11 ng/ml and the R.S.D. is 2.1%. The performance can be improved by using derivative spectrometry.
Keywords:derivative spectrometry  palladium  1,2-diaminoanthra-quinone-  /content/hh78528g33207128/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >-cyclodextrin
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