Hydrogenation and conformational analysis of (1<Emphasis Type="Italic">R</Emphasis>,2<Emphasis Type="Italic">R</Emphasis>,6<Emphasis Type="Italic">S</Emphasis>)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol |
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| Authors: | O V Ardashov A M Genaev I V Il’ina D V Korchagina K P Volcho N F Salakhutdinov |
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| Institution: | 1.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division,Russian Academy of Sciences,Novosibirsk,Russia |
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| Abstract: | Hydrogenation of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol was studied. Nickel chloride-sodium tetrahydridoborate system turned
out to selectively reduce the double bond in the isopropenyl group. The results of conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol and its partly and completely hydrogenated derivatives were in a good
agreement with the NMR data. |
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