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一种可用于光降解的纳米氧化锌油水分离网
引用本文:卢飞,陈雨宁,刘娜,曹莹泽,冯琳.一种可用于光降解的纳米氧化锌油水分离网[J].高等学校化学学报,2014,35(2):368-371.
作者姓名:卢飞  陈雨宁  刘娜  曹莹泽  冯琳
作者单位:清华大学化学系, 北京 100084
基金项目:国家自然科学基金(批准号:51173099)资助.
摘    要:通过低温水热法在钢丝网上生长六棱柱形的氧化锌纳米柱.包覆了氧化锌纳米柱的钢丝网具有水下超疏油的特殊浸润性,并可用于油水分离.滤网在室温常压下可对含有汽油、柴油和原油等油水混合物进行高效快速分离,分离效率可达98%以上.材料可以承受1.4 kPa的油层压力且可反复使用.由于氧化锌的光响应性强,滤网可快速降解水中的亚甲基蓝,2 h的降解率可达80%.包覆了氧化锌纳米柱的钢丝网具备同时进行油水分离和降解环境中污染物的能力,是一种新型多功能水处理材料.

关 键 词:氧化锌  油水分离  光降解  水下超疏油
收稿时间:2013-06-27

Multifunctional Zinc Oxide-coated Mesh for Oil/Water Separation and Pollutant Degradation
LU Fei,CHEN Yuning,LIU Na,CAO Yingze,FENG Lin.Multifunctional Zinc Oxide-coated Mesh for Oil/Water Separation and Pollutant Degradation[J].Chemical Research In Chinese Universities,2014,35(2):368-371.
Authors:LU Fei  CHEN Yuning  LIU Na  CAO Yingze  FENG Lin
Institution:Department of Chemistry, Tsinghua University, Beijing 100084, China
Abstract:With an operation of low-temperature hydrothermal treatment, a steel mesh was coated with hexagon-shaped nanorods of zinc oxide. The as-prepared mesh shows good wettability of underwater superoleophobicity to the droplet of 1,2-dichloroethane, making it possible for the use in oil/water separation. Mixture of water with various kinds of oil such as gasoline, diesel and petroleum ether can be separated rapidly with a high separation efficiency of 98%.The mesh could suffer an oil pressure of 1.4 kPa, with the oil thickness of 21 cm. Depending on the UV-response property of zinc oxide, the mesh can also be used in the degradation of methylene blue, which makes it a multifunctional material for water treatment.
Keywords:Zinc oxide  Oil/water separation  Photo-degradation  Oleophobicity in water
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