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EPR investigation of two types of Syrian's natural zeolites
Authors:SS Soulayman  GM Smith
Institution:a Department of Applied Physics, Higher Institute of Applied Sciences and Technology, P.O. Box 31983, Damascus, Syria
b School of Physics and Astronomy, University of St-Andrews, North Haugh, St-Andrews, Fife KY16 9SS, Scotland, UK
Abstract:Two different samples of natural zeolite have been investigated by X-band electron paramagnetic resonance (EPR) spectroscopy. The observed EPR spectra are typical to those observed for Fe3+ and Mn2+ ions. The lines, related to the iron, are observed, respectively at g≈4.3 and g≈2. The observed six lines, at g≈2, are the hyperfine structure due to the Mn2+ ions. The simulation of the experimental EPR spectra suggests that both of the manganese and the iron are present in more one site. The temperature dependence of the EPR spectra has been also investigated. The nature of the different sites involved in the EPR absorption is discussed.
Keywords:A  Natural zeolite  D  Electron paramagnetic resonance
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