Synthesis of sulfonamide-substituted phthalocyanines |
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Authors: | Eliana FA Carvalho Mrio JF Calvete Augusto C Tom Jos AS Cavaleiro |
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Institution: | aDepartment of Chemistry/QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal |
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Abstract: | The synthesis and characterization of new phthalocyanines bearing eight N-alkyl or N-aryl sulfonamide groups is described. The synthetic route involves the chorosulfonation of 4,5-diphenoxyphthalonitrile with chlorosulfonic acid and reaction of the resulting 4,5-bis(p-chlorosulfonylphenoxy)phthalonitrile with amines. The sulfonamide-substituted phthalonitriles are then cyclotetramerized to yield the title compounds in good yields (50–83%). |
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Keywords: | Phthalocyanines Phthalonitriles Chlorosulfonation Sulfonamides |
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