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Wick’s theorem and reconstruction schemes for reduced density matrices
Authors:Chen Feiwu
Affiliation:(1) Department of Chemistry, University of Science and Technology Beijing, Beijing, 100083, China
Abstract:We first obtained a closed form of the Wick’s theorem expressed in Grassman wedge product, which is similar to a binomial expansion. With this new expansion, new reconstruction schemes for reduced density matrices are derived rigorously. The higher order reduced density matrices are systematically decomposed into a sum of the lower order reduced density matrices which could be used to solve the contracted Schr?dinger equation.
Keywords:reduced density matrix  Wick’  s theorem  occupation number  Schr?dinger equation
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