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New chemosensor for larger guests based on modified cyclodextrin bearing seven hydrophobic chains each with a hydrophilic end group
Authors:Hiroshi Ikeda  Takumi Sugiyama  Akihiko Ueno
Institution:(1) Department of Bioengineering, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259-B-44 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan
Abstract:A new chemosensor for larger guests was prepared. The new chemosensor bears hydrophobic units at the primary hydroxy side and a dansyl unit at the secondary hydroxy side of β-cyclodextrin. Due to the hydrophobic units, the new chemosensor is sensitive to large or slender guests such as SDS and insensitive to 1-adamantanol, which is a good guest for the natural β-CD.
Keywords:Cyclodextrin  Chemosensor  Molecular recognition  Fluorescence
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