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三氧化钼纳米带/石墨烯纳米复合材料的简单制备及其在超级电容器中的应用
引用本文:李会华,宋娟,周锦华,曾文进,冯晓苗.三氧化钼纳米带/石墨烯纳米复合材料的简单制备及其在超级电容器中的应用[J].无机化学学报,2016,32(11):2041-2048.
作者姓名:李会华  宋娟  周锦华  曾文进  冯晓苗
作者单位:有机电子与信息显示国家重点实验室培育基地, 南京邮电大学信息材料与纳米技术研究院;材料科学与工程学院, 南京 210023,有机电子与信息显示国家重点实验室培育基地, 南京邮电大学信息材料与纳米技术研究院;材料科学与工程学院, 南京 210023,有机电子与信息显示国家重点实验室培育基地, 南京邮电大学信息材料与纳米技术研究院;材料科学与工程学院, 南京 210023,有机电子与信息显示国家重点实验室培育基地, 南京邮电大学信息材料与纳米技术研究院;材料科学与工程学院, 南京 210023,有机电子与信息显示国家重点实验室培育基地, 南京邮电大学信息材料与纳米技术研究院;材料科学与工程学院, 南京 210023
基金项目:教育部创新团队(No.IRT1148)、国家自然科学基金(No.20905038,61504066)、江苏省自然科学基金(No.BK20141424,BK20150838)、东南大学生物电子学国家重点实验室(No.I2015010)和江苏省六大人才高峰(No.2015-JY-015)资助。
摘    要:采用简单的超声自组装法制备了石墨烯/三氧化钼纳米带复合材料。最终产物的组成和结构采用多种不同的手段进行了表征,包括扫描电镜、透射电镜、X射线衍射、拉曼光谱以及热分析等。该复合材料可以用作超级电容器电极材料。电化学实验结果表明石墨烯/三氧化钼纳米带复合材料比电容可达到285.5 F·g-1,且在电流密度为1 A·g-1时经过1 000次循环后其电容值能保持初始值的99.5%.

关 键 词:三氧化钼  石墨烯  纳米复合材料  超级电容器
收稿时间:2016/5/23 0:00:00
修稿时间:2016/8/17 0:00:00

MoO3 Nanobelts/Graphene Nanocomposites:Facile Synthesis and Application in Supercapacitors
LI Hui-Hu,SONG Juan,ZHOU Jin-Hu,ZENG Wen-Jin and FENG Xiao-Miao.MoO3 Nanobelts/Graphene Nanocomposites:Facile Synthesis and Application in Supercapacitors[J].Chinese Journal of Inorganic Chemistry,2016,32(11):2041-2048.
Authors:LI Hui-Hu  SONG Juan  ZHOU Jin-Hu  ZENG Wen-Jin and FENG Xiao-Miao
Institution:Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials and School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China,Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials and School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China,Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials and School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China,Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials and School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China and Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials and School of Materials Science & Engineering, Nanjing University of Posts & Telecommunications, Nanjing 210023, China
Abstract:The MoO3 nanobelts/graphene nanocomposites were prepared via facile ultrasonic self-assembly method. The composition and structure of the final product were characterized by various characterization techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectra, and thermogravimetric analysis (TGA). The composites could be used as supercapacitive electrode materials. The electrochemical results showed that the specific capacitance of MoO3 nanobelts/graphene nanocomposite was 285.5 F·g-1. Furthermore, the prepared supercapacitor nearly remained 99.5% of its initial capacitive value after 1 000 cycles at a current density of 1 A·g-1 showing its excellent cycle stibiliy.
Keywords:MoO3  graphene  nanocomposites  supercapacitor
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