Equilibrium conditions of clathrate hydrates formed from carbon dioxide and aqueous acetone solutions |
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Authors: | Tatsuo Maekawa |
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Institution: | Institute for Geo-Resources and Environment, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 7, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8567, Japan |
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Abstract: | Equilibrium conditions of clathrate hydrates formed from carbon dioxide and aqueous acetone solutions were experimentally measured at temperatures between 269.2 and 281.4 K and pressures up to 3.98 MPa. The acetone concentrations in solutions were investigated from 0.04 to 0.40 mass fractions. The experimental results suggested a transition in hydrate structure from structure I to another structure for acetone solutions between 0.04 and 0.12 mass fractions of acetone. The hydrate structure was suggested to be structure II which was the most stable with a 0.16 mass fraction acetone solution. For more than 0.16 mass fraction of acetone, the equilibrium conditions of the hydrate were shifted to lower temperatures as acetone concentrations increased. |
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Keywords: | Clathrate hydrate Gas hydrate Carbon dioxide Acetone Phase equilibria |
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