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Analytical applications of Raman spectroscopy
Authors:Kudelski Andrzej
Affiliation:Key Laboratory of Eco-Chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China
Abstract:In this article interaction of transition metal complexes with DNA and its applications in electrochemical DNA biosensors as hybridization indicator or electroactive marker of DNA are reviewed. Special emphasis has been given to the efforts for the development of new transition metal complexes and their interaction to DNA. DNA and polymers covalently conjugated with transition metal complexes were also reviewed.
Keywords:DNA, deoxyribonucleic acid   ssDNA, single-stranded DNA   dsDNA, double-stranded DNA   bpy, 2,20-bipyridine   phen, 1,10-phenanthroline   bipy, 2,20-bipyridine   PYNI, 2-(20-pyridyl)naphthoimidazole   CT-DNA, calf thymus DNA   dta, 3-(pyrazin-2-yl)-as-triazino[5,6-f]acenaphthylene   dpt, 3-(pyrazin-2-yl)-as-triazino[5,6-f]phenanthrene   ddt, 3-(pyrazin-2-yl)-5,6-diphenyl-as-triazine   CD, circular dichroism   CNOIP, 2-(2-chloro-5-nitrophenyl)imidazo[4,5-f][1,10]phenanthroline   HPIP, 2-(2-hydroxyphenyl)imidazo[4,5-f][1,10]phenanthroline   DPPZ, dipyrido[3,2:α-2&prime  -3&prime  :c]-phenazine   TAPTP, 4,5,9,18-tetraazaphenanthreno-[9,10-b]triphenylene   PMIP, 2-(4-methylphenyl)imidazo[4,5-f]1,10-phenanthroline   Dmp, 2,9-dimethyl-1,10-phenanthroline   OBIP, 2-(2-bromophenyl)imidazo[4,5-f]-1,10-phenanthroline   PBIP, 2-(4-bromophenyl)imidazo[4,5-f]-1,10-phenanthroline   Me4phen, 3,4,7,8-tetra-methyl-1,10-phenanthroline   ip, imidazo[4,5-f][1,10]phenanthroline   pip, 2-phenylimidazo[4,5-f][1,10]phenanthroline   hpip, 2-(2-hydroxyphenyl)imidazo[4,5-f][1,10]phenanthroline   Dip, 4,7-diphenyl-1,10-phenanthroline   qdppz, naphtha[2,3-a]dipyrido[3,2-h:2&prime  ,3&prime  -f]phenazine-5,18-dione   Hqdppz, 5,18-dihydroxynaphtho[2,3-a]dipyrido[3,2-h:2&prime  ,3&prime  -f]phenazine   py, pyridine   dppz, dipyrido[3,2-a:2&prime  ,3&prime  -c]phenazine]   FID, fluorescent intercalator displacement   Hcmbpy, 4-carboxy-4&prime  -methyl-2,2&prime  -bipyridine   Dafone, 4,5-diazafluorene-9-one   DPV, differential pulse voltammetry   HIV, human immunodeficiency virus   bbt, bis(N-benzyl-benzotriazole)dichloro   PVP, poly(4-vinylpyridine)   PVP-[Os(5,6-dmphen)2Cl]2+, 5,6-dmphen     5,6-dimethyl-1,10-phenanthroline   Os, osmium   PEM, polyelectrolyte multilayer   Au, gold   GCE, glassy carbon electrodes   Os-PVP, [Os(bpy)2CI]2+-PVP   AA, ascorbic acid   phen-dione, 1,10-phenantroline-5,6-dione   DA-bpy, 4-diamino-2,2-bipyridine   DPPZ, dipyrido[3,2-a:2,3-c]phenazine   Im, imidazole   Teph, terephthalate   Mim, 1-methylimidazole   NCS, thiocyanate   CV, cyclic voltammetry
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