| 一种1, 10-菲啰啉-5, 6-二酮及其单肟的高效合成方法 |
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| 引用本文： | 张智斌,闫文鹏,樊美公. 一种1, 10-菲啰啉-5, 6-二酮及其单肟的高效合成方法[J]. 应用化学, 2005, 22(1): 103-104 |
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| 作者姓名： | 张智斌 闫文鹏 樊美公 |
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| 作者单位： | 中国科学院理化技术研究所,北京,100101 |
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| 基金项目： | 国家高技术研究发展计划(863计划)，国家自然科学基金 |
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| 摘 要： | 1,10-菲啰啉-5,6-二酮(2)与1,10-菲啰啉-5,6-二酮单肟(3)作为稠杂环共轭配体,既具有良好的配位特性,又是重要的有机合成反应中间体.由化合物2和它的衍生物与金属离子形成的配合物可以用于抗肿瘤药物、DNA探针、非线性光学材料、超分子组装分子骨架、自旋交叉配合物等许多领域.化合物3则用于有机光致变色化合物螺噁嗪的合成.
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| 关 键 词： | 菲啰啉二酮 菲啰啉二酮单肟 合成 |
| 文章编号： | 1000-0518(2005)01-0103-02 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2004-02-20 |
An Efficient Synthesis Method for 1,10-Phenanthroline-5,6-dione and Its Mono-oxime |
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| ZHANG Zhi Bin,YAN Wen Peng ,FAN Mei Gong. An Efficient Synthesis Method for 1,10-Phenanthroline-5,6-dione and Its Mono-oxime[J]. Chinese Journal of Applied Chemistry, 2005, 22(1): 103-104 |
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| Authors: | ZHANG Zhi Bin YAN Wen Peng FAN Mei Gong |
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| Affiliation: | ZHANG Zhi Bin,YAN Wen Peng *,FAN Mei Gong |
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| Abstract: | phenanthroline(1) was oxidized by a mixture of concentrated sulfuric acid and concentrated nitric acid in the presence of sodium bromide to yield 1,10 phenanthroline 5,6 dione(2) in 90%. Compound 2 gave a mono oxime(3) hydrochloric salt in nearly quantitive amount by reacting with equal molar hydroxylamine hydrochloride. The structures of the compounds were characterized by IR and 1 H NMR spectroscopy. The method is more simple and efficient. |
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| Keywords: | phenanthrolinedione phenanthrolinedione mono oxime synthesis |
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