Inhibition of the electrochemistry of ferrocenes by polyamine dendrimers and the key role of hydrogen-bonding with hydroxy groups |
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| Authors: | Daniel Marie-Christine Ruiz Aranzaes Jaime Astruc Didier |
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| Affiliation: | Nanosciences and Catalysis Group, LCOO, UMR CNRS No 5802, Université Bordeaux I, 33405, Talence Cedex, France. |
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| Abstract: | Commercial DSM polyamine dendrimers inhibit the observation of the cyclic voltammetry (CV) of simple ferrocenes all the more as they are larger (marked dendritic effect); the CV is re-established, however, if a OH-containing group is present in the ferrocene derivative. |
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