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聚醚聚氨酯/环氧树脂互穿网络高聚物的研究(Ⅰ)
引用本文:赵彦群,李玉玮,王静媛,汤心颐,于旻,杨毓华.聚醚聚氨酯/环氧树脂互穿网络高聚物的研究(Ⅰ)[J].高等学校化学学报,1988(6).
作者姓名:赵彦群  李玉玮  王静媛  汤心颐  于旻  杨毓华
作者单位:吉林大学化学系 (赵彦群,李玉玮,王静媛,汤心颐),长春应用化学研究所 (于旻),长春应用化学研究所(杨毓华)
摘    要:互穿网络高聚物(IPN)是两种或多种交联聚合物的共混体。由于两种聚合物网络相互贯穿和缠结,链节间的永久锁结产生强迫互容,使不同聚合物达到最紧密混合,最大限度地控制多相体系的相分离,IPN材料显示不寻常的耐热,耐溶剂和高强度等特点,远远超过其聚合物本身的性能。在IPN中,两网络相互贯穿程度越高,相分离越低,这主要取决于构成聚合物本身的相容性和最终网络结合方式。本文通过改变组

关 键 词:PU/EP  互穿网络

The Investigation on Polyurethane and Epoxyresin Interpenetrating Polymer Networks
Zhao Yaniun,Li Yuwei,Wang Jingyuan,Tang Xinyi.The Investigation on Polyurethane and Epoxyresin Interpenetrating Polymer Networks[J].Chemical Research In Chinese Universities,1988(6).
Authors:Zhao Yaniun  Li Yuwei  Wang Jingyuan  Tang Xinyi
Abstract:In this paper, the synthesis of interpenetrating polymer nelworks(IPN) based on polyurethane and epoxide by simultaneous polymerization, the influence of various component on their morphology, gh-ss transition behavior,mechanical properties and thermostability are reported. The results show that PU/EP = 25/75exhibited the best, mechanical properties and thermostability due to the high degree of interpenetration among the networks. PU/Ep = 50/50 exhibited obvious phase separation and the poorest mechnical properties.
Keywords:PU/EP  Interpenetrating  
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