Comparison of pressurized liquid extraction and microwave assisted extraction for the determination of organochlorine pesticides in vegetables |
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| Authors: | M Barriada-Pereira MJ González-Castro P López-Mahía D Prada-Rodríguez E Fernández-Fernández |
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| Institution: | a University Institute of Environment, Pazo de Lóngora, Liáns, Oleiros, A Coruña, E-15179, Spain
b Department of Analytical Chemistry, University of A Coruña, Campus da Zapateira, s/n, E-15071, A Coruña, Spain |
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| Abstract: | A method to determine organochlorine pesticides in horticultural samples (lettuce, tomato, spinach, potato, turnip leaf and green bean) using pressurized liquid extraction (PLE) is described and compared with microwave assisted extraction (MAE). Significant parameters affecting PLE procedure such as temperature, static extraction time and extraction solvent were optimised and discussed. Clean-up of extracts was performed by solid phase extraction (SPE) using a carbon cartridge as adsorbent. Pesticides were determined by gas chromatography and electron capture detection (GC-ECD). Analytical recoveries obtained were ca. 100% and the relative standard deviations were lower than 15% for most of the studied pesticides with the proposed methods in each analysed matrix. |
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| Keywords: | Organochlorine pesticides Vegetable samples Pressurized liquid extraction Microwave assisted extraction Solid-phase extraction |
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