EFFECT OF MORPHOLOGICAL STRUCTURE OF AMINOMETHYL POLYSTYRENE RESIN ON THE CATALYTIC PROPERTIES OF POLYMERSUPPORTED RUTHENIUM COMPLEXES |
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| Authors: | Ren-ren Wang Jia-qin Wang Ce Luo Zhe Zhang Bi-tao Su Zi-qiang Lei Key Laboratory of Polymer Materials of Gansu Province College of Chemistry Chemical Engineering Northwest Normal University Lanzhou China |
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| Institution: | Ren-ren Wang Jia-qin Wang Ce Luo Zhe Zhang Bi-tao Su Zi-qiang Lei Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry , Chemical Engineering,Northwest Normal University,Lanzhou 730070,China |
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| Abstract: | Polymer-supported ruthenium complexes (p)-Phen-Ru-①,(p)-Phen-Ru-②,(P)-Phen-Ru-③,(p)-Phen-Ru-④,morphological structures as supports.A variety of alcohols were oxidized efficiently into the corresponding ketones,carboxylic acids or aldehydes with iodosylbenzene (PhIO) catalyzed by aminomethyl polystyrene-supported ruthenium complexes under mild reaction conditions in acetonitrile.The influences of morphological structure of the polymer supporters on the catalytic properties of these metal complexes were investigated in detail. |
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| Keywords: | Alcohol oxidation Ru-immobilized catalyst PS-carrier Morphological structure |
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