Indium(III) acetate-catalyzed intermolecular radical addition of organic iodides to electron-deficient alkenes |
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Authors: | Miura Katsukiyo Tomita Mitsuru Ichikawa Junji Hosomi Akira |
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Affiliation: | Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. miura@chem.tsukuba.ac.jp |
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Abstract: | In the presence of phenylsilane and a catalytic amount of indium(III) acetate, organic iodides added to electron-deficient alkenes in ethanol at room temperature. Both simple and functionalized organic iodides were applicable to this reaction. A plausible reaction mechanism involves the formation of indium hydride species by hydride transfer from silicon to indium and an indium hydride-mediated radical chain process. |
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