Not the enolate Claisen rearrangement. A surprising route to the “right-wing” of indanomycin (X-14547A) |
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| Authors: | Steven D Burke David M Armistead K Shankaran |
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| Institution: | Department of Chemistry, University of South Carolina Columbia, South Carolina 29208 USA |
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| Abstract: | A synthesis of the “right-wing” equivalent 22 of the ionophore antibiotic indanomycin is described, wherein an unexpected retro hetero Diels-Alder/intramolecular Diels-Alder pathway gives the desired product of the planned Claisen 3,3]-shift. |
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