Binuclear copper(II) complexes of 5-nitrosalicylaldehyde N(3)-substituted thiosemicarbazones |
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Authors: | Douglas X West Michelle M Salberg Gordon A Bain Anthony E Liberta Jesús Valdés-Martínez Simón Hernández-Ortega |
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Institution: | (1) Department of Chemistry, Illinois State University, IL61790 Normal, USA;(2) Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, México DF;(3) Ciudad Universitaria, 04510 Coyoacán, México DF |
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Abstract: | Summary Binuclear copper(II) complexes with six 5-nitrosalicylaldehyde N(3)-substituted thiosemicarbazones have been prepared and characterized. I.r., electronic and e.s.r. spectra of the complexes, as well as i.r., electronic, and 1H-and 13C-n.m.r. spectra of the thiosemicarbazones, have been obtained. The crystal structure of a monomeric copper(II) complex of 5-nitrosalicylaldehyde piperidyl-thiosemicarbazone, H25NO2Sapip, grown from DMF solution, has been solved. Neither the thiosemicarbazones or their binuclear copper(II) complexes show growth inhibitory activity against Aspergillus niger, but the copper(II) complexes show some activity against the fungus Paecilomyces variotii. |
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