Kinetics of reactions between arylnitroso oxides and methyl vinyl ketone |
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Authors: | Email author" target="_blank">E?M?ChainikovaEmail author R?L?Safiullin |
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Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, 450054, Bashkortostan, Russia |
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Abstract: | The kinetics of the reactions of phenylnitroso oxide, (4-methylphenyl)nitroso oxide, (4-methoxyphenyl) nitroso oxide, 4-(N, N -dimethylamino)phenylnitroso oxide, (4-chlorophenyl)nitroso oxide, (4-bromophenyl) nitroso oxide, and (4-nitropenyl)nitroso oxide with methyl vinyl ketone in acetonitrile at 295 K was studied. With the use of 4-CH3O-C6H4-NOO as an example, it was found that only the trans isomers of nitroso oxides entered into the reaction. The rate constants of the reactions of the trans isomers of nitroso oxides with methyl vinyl ketone were measured. A linear correlation between the logarithms of reaction rate constants and the electronic properties of substituents in the aromatic rings of nitroso oxides on the Hammett scale was established: ρ = 1.11 ± 0.08; r = 0.990. |
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