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Selective oxidation of cyclopentene catalyzed by Pd(CH3COO)2-NPMoV under oxygen atmosphere |
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| Authors: | Chao Sui Guang Lu Xin-yong Li Zhen-ping Qu Xue-jun Zou Guo-hua Chen |
| Affiliation: | (1) Key Laboratory of Industrial Ecology and Environmental Engineering, MOE and State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116023, China;(2) Department of Chemical Engineering, the Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China |
| Abstract: | The selective oxidation of cyclopentene to cyclopentanone catalyzed by Pd(CH3COO)2-NPMoV was investigated under atmospheric oxygen in aqueous acetonitrile acidified by CH3SO3H. It was shown that the conversion of cyclopentene and the yield of cyclopentanone was nearly 100% and 94.6%, respectively, under the optimized reaction condition. |
| Keywords: | Cyclopentene cyclopnetanone Pd(CH3COO)2 NPMoV |
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