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Recent Advances in Imidazoliumyl‐Substituted Phosphorus Compounds
Authors:Dr Kai Schwedtmann  Prof Giuseppe Zanoni  Prof Dr Jan J Weigand
Institution:1. Faculty of Chemistry and Food Chemistry, TU Dresden, Chair of Inorganic Molecular Chemistry, Dresden, Germany;2. Department of Chemistry, University of Pavia, Pavia, Italy
Abstract:This review aims to highlight the recent developments in the chemistry of selected imidazoliumyl‐substituted phosphorus compounds. The synthetic approaches for their preparation with phosphorus in various oxidation states and coordination environments are discussed. Their intriguing properties and versatile chemistry strongly depends on the bonding motif at the P atoms, which is given special focus.
Keywords:coordination chemistry  imidazoliumyl substituents  N-heterocyclic carbenes  phosphorus  phosphorus-centered cations
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