[(18‐Crown‐6)K][Fe(1)Cl(1)4]0.5[Fe(2)Cl(2)4]0.5: A Multifunctional Molecular Switch of Dielectric,Conductivity and Magnetic Properties |
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Authors: | Yuan‐Bo Tong Prof Zheng‐Fang Tian Prof Hai‐Bao Duan Zhong‐Peng Zhu Wei He Tian‐Yu Hong Prof Gui Yu Prof Yu‐Jian He Prof Jing‐Kui Yang |
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Institution: | 1. School of Chemical Sciences, University of Chinese Academy of Sciences., Beijing, P. R. China;2. Hubei Key Laboratory for Processing and Application of Catalytic Materials, Huanggang Normal University, Huanggang, Hu Bei Province, P. R. China;3. School of Environmental Science, Nanjing Xiaozhuang University, Nanjing, P. R. China;4. Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China |
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Abstract: | Multifunctional materials that exhibit different physical properties in a single phase have potential for use in multifunctional devices. Herein, we reported an organic–inorganic hybrid compound (18‐crown‐6)K]Fe(1)Cl(1)4]0.5Fe(2)Cl(2)4]0.5 ( 1 ) by incorporating KCl and FeCl3 into a 18‐crown‐6 molecule, which acts as a host of the six O atoms providing a lone pair of electrons to anchor the guest potassium cation, and FeCl4]? as a counterion for charge balance to construct a complex salt. This salt exhibited a one‐step reversible structural transformation giving two separate high and low temperature phases at 373 K, which was confirmed by systematic characterizations including differential scanning calorimetry (DSC) measurements, variable‐temperature structural analyses, and dielectric, impedance, variable‐temperature magnetic susceptibility measurements. Interestingly, the structural transformation was coupled to both hysteretic dielectric phase transition, conductivity switch and magnetic‐phase transition at 373 K. This result gives an idea for designing a new type of phase‐transition materials harboring technologically important magnetic, conductivity and dielectric properties. |
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Keywords: | crystal engineering heterometallic complexes organic-inorganic hybrid composites structure-phase transition supramolecular chemistry |
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