Formation of Supramolecular Nanotubes by Self‐assembly of a Phosphate‐linked Dimeric Anthracene in Water |
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Authors: | Dr. Hao Yu Mattia Sabetti Prof. Dr. Robert Häner |
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Affiliation: | Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland |
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Abstract: | The assembly of supramolecular polymers from a phosphodiester‐linked dimeric anthracene is described. AFM and TEM imaging reveals that the supramolecular polymers self‐assemble into nanotubes in water. Subsequent photodimerization experiments indicate that the supramolecular polymerization occurs via end‐to‐end stacking rather than an interdigitation arrangement of the building blocks. |
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Keywords: | anthracene dimerization nanotube phosphate-linkage self-assembly supramolecular polymers |
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