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Formation of Supramolecular Nanotubes by Self‐assembly of a Phosphate‐linked Dimeric Anthracene in Water
Authors:Dr Hao Yu  Mattia Sabetti  Prof Dr Robert Häner
Institution:Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland
Abstract:The assembly of supramolecular polymers from a phosphodiester‐linked dimeric anthracene is described. AFM and TEM imaging reveals that the supramolecular polymers self‐assemble into nanotubes in water. Subsequent photodimerization experiments indicate that the supramolecular polymerization occurs via end‐to‐end stacking rather than an interdigitation arrangement of the building blocks.
Keywords:anthracene dimerization  nanotube  phosphate-linkage  self-assembly  supramolecular polymers
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