|
|||||
|
|
Shape‐Controlled Surface‐Coating to Pd@Mesoporous Silica Core–Shell Nanocatalysts with High Catalytic Activity and Stability |
|
| Authors: | Dr. Jie Ying Prof. Christoph Janiak Yu‐Xuan Xiao Hao Wei Prof. Xiao‐Yu Yang Prof. Bao‐Lian Su |
| Affiliation: | 1. State Key Laboratory Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China;2. Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universit?t Düsseldorf, Düsseldorf, Germany;3. Laboratory of Inorganic Materials Chemistry (CMI), University of Namur, Namur, Belgium |
| Abstract: | Cubic Pd nanocrystals with shape‐controlled mesoporous silica shells have been theoretically designed and successfully synthesized for investigating the effect of a porous nanoshell on catalytic performance of the core. Cubic Pd@cubic mesoporous silica keeps activity of all facets and shows highest catalytic activity and enhanced reusability in the hydrogenation of nitrobenzene. |
| Keywords: | core– shell structures heterogeneous catalysis mesoporous materials palladium shape control |