The thermal decomposition reactions of [Co(en)n(phen)m]Cl3 complexes |
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| Authors: | R. Bucci, A. D. Magrì , A. L. Magrì ,A. Messina |
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| Affiliation: | Institute of Analytical Chemistry, University of Rome, Rome Italy |
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| Abstract: | The thermal behaviour of [Co(en)n(phen)m]Cl3 complexes has been studied using thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA) in air, nitrogen and oxygen atmospheres. The effect of the stoichiometry of the complexes and that of the gas atmosphere in the furnace chamber on the thermal decomposition reaction is evidenced and discussed. The following thermal stability order has been found [Co(en)3]Cl3 [Co(en)2(phen)]Cl3 > [Co(en)(phen)2]Cl3 [Co(phen)3]Cl3 |
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| Keywords: | To whom correspondence should be addressed. |
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