Chiral hybrid metal-organic dendrimers |
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Authors: | Jiang Hua Lee Suk Joong Lin Wenbin |
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Institution: | Department of Chemistry, CB #3290, University of North Carolina, Chapel Hill, North Carolina 27599, USA. |
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Abstract: | structure: see text] New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4'-6-(2,2'-dihydroxy-1,1'-binaphthyl)]-2,2':6'2' '-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the Ru(terpy)(2)](2+) unit. |
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