Hydrogenation catalysts based on palladium bisacetylacetonate and lithium tetrahydroaluminate: Formation mechanism and reasons for modified effect of water |
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Authors: | L. B. Belykh Yu. Yu. Titova A. V. Rokhin L. N. Belonogova F. K. Shmidt |
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Affiliation: | (1) Irkutsk State University, Irkutsk, Russia;(2) Institute of Petro- and Coal-Chemical Synthesis, Irkutsk State University, Irkutsk, Russia |
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Abstract: | Mechanism of formation, nature of activity, and properties of species active in hydrogenation catalysis in systems based on Pd(acac)2 and LiAlH4 were studied. The effect consisting in activation of catalytic systems was observed and reasons for the modifying action of water were considered. |
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