| 胶束微观非均相体系与化学发光能量转移 |
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| 引用本文： | 吕超,林金明. 胶束微观非均相体系与化学发光能量转移[J]. 物理化学学报, 2004, 20(Z1): 974-981 |
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| 作者姓名： | 吕超 林金明 |
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| 基金项目： | 国家自然科学基金，国家高技术研究发展计划(863计划) |
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| 摘 要： | 胶束微观非均相体系能提高化学发光的选择性和灵敏度,并且实验操作方便,因此其在化学发光检测技术中的应用已成为研究热点.胶束增敏化学发光是对激发量子效率,荧光量子效率以及反应的速率综合作用的结果.本文综述了正相和反相胶束体系在能量转移型化学发光体系中的应用,同时阐述了胶束与不同发光体系的相互作用.
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| 关 键 词： | 化学发光 正相胶束 反相胶束 能量转移 |
Microheterogeneous System of Micelles and Chemiluminescent Energy Transfer |
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| Abstract. Microheterogeneous System of Micelles and Chemiluminescent Energy Transfer[J]. Acta Physico-Chimica Sinica, 2004, 20(Z1): 974-981 |
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| Authors: | Abstract |
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| Abstract: | In chemiluminescence measurements, an interesting development of analytical significance is the incorporation of micelle into the detection system, which has achievements of multiple benefits such as enhanced sensitivity, improved selectivity and experimental convenience. In this review, normal and reversed micelle enhancement on chemiluminescence(CL) energy transfer is described. The different chemiluminescence systems in conjunction with energy transfer and the interactions with the micelle enhancement are presented. In micelle media, a combination of changes in excitation efficiency, fluorescence efficiency, and the reaction rate of the CL system results in an increase of the CL intensity. |
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| Keywords: | Chemiluminescence(CL) Normal micelles Reversed micelles Energy transfer |
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