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Structure of cyclobutanone

Authors:	William M Stigliani Victor W Laurie LH Scharpen

Institution:	Department of Chemistry, Princeton University, Princeton, New Jersey 08540 USA;Hewlett-Packard Company, Palo Alto, California 94304 USA

Abstract:	The microwave spectra of the ¹⁸O and the α,α,α′,α′-tetradeuterated isotopic species of cyclobutanone have been investigated. Structural parameters determined are $r_{CO} = 1.204 ± 0.006 A ?$ , $r_{CH_{α}} = 1.099 ± 0.003 A ?$ , ∠ H_αCH_α = 109.2 ± 1° with the methylene group tilted toward the carbonyl group by 4.6 ± 0.8°.

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