Crystal structure of a macrocyclic tetraamine isocyanato zinc(II) complex |
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| Authors: | Ki-Young Choi Kang Moon Chun Il-Hwan Suh |
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| Affiliation: | (1) Department of Chemistry, Mokwon University, Taejon, 301-729, Korea;(2) Department of Physics, Chungnam National University, Taejon, 305,764, Korea |
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| Abstract: | The complex, [Zn(L)(NCO)]Cl · 3H2O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane), has been synthesized and structurally characterized. 1 crystallizes in the monoclinic system, space group P21/n with a = 10.530(3), b = 9.315(2), c = 27.188(3) Å,  = 92.58(1)°, V = 2664.1(9)Å3, and Z = 4. The zinc atom is in a distorted squarepyramidal environment with the four nitrogen atoms of the macrocycle and one nitrogen atom of the isocyanate ligand. |
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| Keywords: | Crystal structure macrocyclic tetraamine isocyanato zinc(II) complex |
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