The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl) |
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| Authors: | García Felipe Hopkins Alexander D Humphrey Simon M McPartlin Mary Rogers Michael C Wright Dominic S |
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| Institution: | Chemistry Department, Cambridge University, Lensfield Road, Cambridge, UK CB2 1EW. |
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| Abstract: | The low-temperature reaction of MeSiCl3 with 2-Li-C5H4N (1:3 equivalents) in thf gives MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl), containing the first example of a Si-bridged tris(pyridyl) ligand. |
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