Crystallographic observation of an olefin photodimerization reaction that takes place via thermal molecular tumbling within a self-assembled host |
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| Authors: | Takaoka Kanji Kawano Masaki Ozeki Tomoji Fujita Makoto |
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| Institution: | Department of Applied Chemistry, School of Engineering, University of Tokyo and CREST, Japan Science ad Technology Corporation (JST), 7-3-1 Hongo, Tokyo 113-8656, Japan. |
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| Abstract: | In situ crystallography reveals that the solid state 2 + 2] photodimerization of acenaphthylene in a coordination cage takes place smoothly without preorganizaiton of reaction centers at a preferred geometry, because the substrate tumbles thermally in the large hollow of the cage. |
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