超细粉体二硫纶·菲咯啉二酮混配钴(Ⅱ)配合物的荧光特性和光敏性研究 |
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引用本文: | 潘庆才,彭正合.超细粉体二硫纶·菲咯啉二酮混配钴(Ⅱ)配合物的荧光特性和光敏性研究[J].影像科学与光化学,2005,23(1). |
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作者姓名: | 潘庆才 彭正合 |
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作者单位: | 黄淮学院,河南,驻马店,463000;武汉大学,化学与分子科学学院,湖北,武汉,430072 |
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基金项目: | 国家自然科学基金,河南省教育厅科研项目 |
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摘 要: | 报道了二氰基二硫纶·菲咯啉 5,6 二酮混配钴(Ⅱ)配合物CoLL′(L=mnt2-.mnt2-为1,2 二氰基乙烯 1,2 二硫醇离子.L′=phen 5,6 dione,1,10 菲咯啉 5,6 二酮)的合成和标题配合物的电子吸收光谱、电子发射光谱.研究了CoLL′对CdS的光敏化作用与其电子光谱间的关系.
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关 键 词: | 二硫纶 菲咯啉二酮 钴 配合物 光敏性 |
Study on the Fluorescence and Photosensitivity of Superfines Cobalt Complexes of Dithiolate and Phenanthroline-5,6-Dione |
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Abstract: | The electronic absorption spectra and emission spectra of complexes CoLL′ (L=mnt~(2-),1,2-dicyano-1,2-ethylenedithiolate or maleonitriledithiolate.L′=phen-5,6-dione,1,10-phenanthroline-5,6-dione),and photosensitivity of CdS doped with CoLL′ were reported.The correlation between photosensitization of complexes CoLL′ to CdS and their electronic spectra were studied. |
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Keywords: | dithiolate phenanthroline-5 6-dione cobalt complex fluorescence photosensitivity |
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