Reactions of the radical cations of aliphatic aldehydes in freon matrices |
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Authors: | V N Belevskii S I Belopushkin V I Feldman |
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Institution: | (1) Faculty of Chemistry, M.V. Lomonosov State University, Moscow, USSR |
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Abstract: | ESR spectra of -irradiated, at –196 °C, solutions of acetic and propionic aldehydes in freon-11 and freon-113 affected by aldehyde concentration, temperature, and the action of light have been studied. It has been shown that the radical cations CH3CHO+ are converted into neutral radicals CH3O and CH3HOH and the cations CH3CH2CHO+. are converted to RO and CH3HCHO due to ion-molecular reactions of proton transfer /CH3O and CH3HCHO/ of hydrogen atom transfer /CH3HOH/. |
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