Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs |
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| Authors: | Wang Hailong Wang Kang Tao Jun Jiang Jianzhuang |
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| Affiliation: | Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China. |
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| Abstract: | Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference. |
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